Saturday 12 March 2016

BIOMOLECULES CLASS XII CHEMISTRY STUDY MATERIAL

CHAPTER 14
BIOMOLECULES
Q1 – Give an example of Vitamin which is (a)Water soluble (b) Fat soluble.
Ans. (a) Vitamin C  (b)Vitamin D.

Q2 – What are anomers?
Ans – Monosaccharide which differ only in the orientation of the ―OH group at C-1.e.g, α-glucose and β-glucose.

Q 3 – Where does the water present in the egg go after boiling the egg?
Ans On boiling during denaturation process water gets adsorbed/absorbed in the denatured proteins.

Q 4 – Give three differences between DNA and RNA.
 Ans -

DNA

RNA
1. It has deoxyribose as sugar.
2. It contains thymine along with adenine, cytosine and guanine as bases.
3. It is responsible for maintaining heredity traits from generation to generation.

1. It contains ribose as sugar.
2.It contains uracil in place of thymine with other bases.
3. It is responsible for protein synthesis.
Q.5 What  are  essential  and  non-essential  amino  acids ?  Give two  examples  of  each  type.
Ans: Essential  amino  acids: Amino  acids  which  cannot  be  synthesized  in  the  body  and  must  beobtained  through  diet  are  known  as essential  amino  acids.Example :Valine  ,  Leucine.
Non-essential  amino  acids: The  amino  acids  which  can  be  synthesized  in  the  body  are 
known  as  non – essential  amino  acids.Example : Glycine , alanine.

Q.6 – What happens when glucose reacts with
(a)HI (b) HNO3 (c)Br2 water
Ans –
(a) C6H1206 + HI ------> n-Hexane C6H14
(b) C6H1206 + HNO3------>Saccharic acid
(c) C6H1206 +Br2 water ----->Gluconic acid
Q.7. – Which types of bonds are present in a protein molecule?
Ans – Peptide bonds, hydrogen bonds, sulphide bonds, ionic bonds etc.
Q.8     Name the enzyme that is used t dissolve blood clots?
Ans       Streptokinase
Q.9  Name two disease caused due to deficiency of enzymes ?
Ans  Albinism and phenylketonuria

Q.10  Write a short note on
(i) Co- enzymes               (ii) Prosthetic groups
Ans   (i) Co –enzymes: - These are usually derived from vitamins such as thiamine, riboflavin, niacin etc. They are loosely held to the protein and can be easily separated by dialysis.
(i)     Prosthetic groups: - They are also derived from vitamins such as biotin but are tightly held to the protein molecule by covalent bonds. They can be separated only by careful hydrolysis.
(ii)    
Q11. Fresh tomatoes are a better source of vit C than that which have been stored for some time. Why?
Ans Vitamin C is destroyed on prolonged exposure to air due to its oxidation.

Q.12 Although Glucose is a covalent compound yet it is soluble in water. Why?
Ans Glucose is a covalent compound but can form H bond with Water molecule because it has OH groups. So it is soluble in to water.









HOTS
Q1.What is denaturation of proteins? Explain with examples.                                             
 Ans.Disruption of the native conformation of a protein by changing its environment like PH value, temperature etc. resulting into loss of its biological activity is called denaturation of proteins. During denaturation, secondary and tertiary structures get destroyed while primary structure remains same e.g., coagulation of egg albumin by boiling.

Q2.Distinguish between globular protein and fibrous protein.
Ans.They both are examples of tertiary proteins made for their specialized role. The differences between them are given below.
 Difference between fibrous proteins and globular proteins
            Fibrous proteins          Globular proteins
1. They are long, elongated, thread-like and asymmetric in shape they are spherical, oval or    
     Elliptical in shape
1.      The peptide chains are held together by strong intermolecular hydrogen bonds       The peptide chains are held together by relatively weak intramolecular hydrogen bonds
2.      They are insoluble in water but soluble in concentrated acids and alkalis      They are soluble in water
3.      Examples: Keratin, Fibroin, Collagen             Examples: Insulin, Casein, Egg albumin, myoglobin, antibodies
 Q 3   Except Vit B 12 , all the vitamins of group B should be supplied regularly in diet. Why ?
Ans  All vitamins of group B are soluble in water and excreted , therefore they should supplied regularly in diet whereas vit B 12 is insoluble in water , therefore it can be stored in body and may not be part of our diet.
Que 4. What is meant by zwitter ion ?
Ans . Amino acids present in a dipoler molecule in which both ions present is called zwitter ion .amino acids are more stable in this form.
Que 5.What is isoelectric point?
Ans.     The isoelectric points (pI)
•           are the pH at which zwitterions have an overall zero charge
•           of nonpolar and polar (neutral) amino acids exist at pH values from 5.1 to 6.3
Q 6. Draw simple Fischer projections of D and L- glucose. Are these enantiomers?
Q.7  Why  cannot  Vitamin C  be  stored  in  our  body ?
Q.8 Name the tow comptometers of starch. How do they differ from each other structurally?
Q.9  Mention  the  type  of  linkage  responsible  for  the  formation  of  the  following  :
              i) Primary structure of proteins                                    ii) Cross linking of polypeptide chains
            iii) Helix formation                                                 iv)  sheet structure
Q.10 Explain the term mutarotation giving an example.



            ANSWERS
Ans-1
        CHO                                                             CHO
   H -|-OH                                                       HO-|- H
HO -|-H                                                            H -|-OH
   H -|-OH                                                       HO-|- H
   H -|-OH                                                      HO -|-H
       CH2OH                                                          CH2OH
D-Glucose                                                    L-Glucose
Yes these two Fischer projections are called enantiomers.
Ans2-  Vitamin c   is  water  soluble  ,  therefore  it  is  readily   excreted  in  urine  and  hence  cannot  be stored  in  the  body.

Ans3-  The two components of starch are:
            i) Amylose                        ii) Amylopectin
Amylose  is  a  straight  chain  polymer  of   glucose  , while  amylopectin  is  a  branched chain  polymer  of  glucose.
Ans4-
Biomolecule
Types  of  linkage
1. primary  structure  of  proteins
- peptide  bond  or peptide linkage
2.Cross  linking  of  polypeptide  chains
- polypeptide  linkage
3. helix  formation
- hydrogen  bonds
4.  sheet  structure

- Intermolecular hydrogen bonds.







Ans5-
The  spontaneous  change  in  specific  rotation  when an  optically  active  substance  is   dissolved  in water is  called  mutarotation. For example, when   glucose is dissolved in water its specific rotation changes because it gets converted into glucose.



VALUE BASED QUESTIONS
Q. 1 Meena’s son who is 2 years old started walking that time she observed that he has bow legs parents consulted a doctor and has suggested some remedy
a)  What is the remedy suggested by the doctor?
b)  Name the   sources in which the mentioned vitamin is present ?
c)   What value you have gained from this?
Ans:-  a)The doctor informed that it was due to the deficiency of vitamin D.He suggested to include food containing more vitamin D in the diet.
b)  Cod liver oil, butter, milk, eggs, liver and meat.
c)  Vitamins play an important role in our day to day  life. Inorder to be healthy we must take vitamins along with carbohydrates, proteins and fat.

Q.2 Humans, monkeys and guinea pigs do not have the enzymes necessary for the synthesis of vitamin C, so they must include the vitamin in their diets. It is also required for the synthesis of collagen, which is the structural protein of skin tendors, connective tissue and bone.
(i) Write structure of vitamin C and the functional groups therein.
(ii) Is it acetic in nature?? What is the common name of vitamin C?
(iii) What is the oxidation product of vitamin C?
Answers)
(i)
(ii) It is acidic due to enolic-OH.
Common name is ascorbic acid.
(iii)
Q. 3 Rahul’s father recovered from a massive heart attack. As follow up doctor gave him Aspirin.
a.                 Why? After some time he started to develop some stomach ache.
Then his wife gave him some butter milk
b.    Why?
c.     What value do you get from this?
Ans:
a) Aspirin is a blood thinner. Hence for a patient suffering from heart attack is given Aspirin.  Aspirin is acetylated salicylic acid. In the presence of acid in the stomach it undergoes hydrolysis to form two acids salicylic acid and acetic acid. This increases the acidity in the
Stomach.                                                                                                                 
b) To neutralize this acidity butter milk is also given.                                             
 c) Being dedicated and faithful.
















No comments: